Lucy
Are you using version 1.0.5 or beta 1.1.0?
1.0.5
can you use other devices, like a pc, to access your over-the-internet Plex server
Yes, if I understand your question.
On my LAN/WLAN, I can access the internet-remote server via my Roku.
Additionally, on this PC...
I have a Plex server on my LAN that Skybox/Oculus Quest 2 can access perfectly.
... I can access internet-remote servers via the Plex webapp on that PC.